catalytic application of an organosuperbase denderon grafted on mesoporous sba-15 and related palladium complex in the aerobic oxidation of alcohols

Authors

hojat veisi

davood kordestani

sami sajjadifar

mona hamelian

abstract

an efficient synthetic method for successful synthesis of amine denderon on sba-15 and related pd (ii) complex has been developed. this modified mesoporous material was characterized by various techniques such as tem, xrd, atomic absorption spectroscopy, n2 adsorption-desorption, and ft-ir. the catalytic activities of the prepared catalysts were investigated by employing aerobic oxidation of alcohols as model reactions. the yields of the products were in the range from 75% to 92%. the catalyst can be readily recovered and reused at least 5 consecutive cycles without significant leaching and loss its catalytic activity. organosuperbase, sba-15, palladium complex, oxidation organosuperbase, sba-15, palladium complex, oxidation

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Journal title:

iranian chemical communication

Publisher: payame noor university (pnu)

ISSN 2423-4958

volume 2

issue Issue 1 (pp. 1-81) 2014

Keywords

[ ' o r g a n o s u p e r b a s e ' , ' s b a ' , 1 5 , ' p a l l a d i u m c o m p l e x ' , ' o x i d a t i o n ' ]

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